分类： 天文学 >> 天文学 提交时间： 2023-02-19
Lixia Yuan
Ji Yang
Fujun Du
Yang Su
Xunchuan Liu
Shaobo Zhang
Yan Sun
Xin Zhou
Qing-Zeng Yan
Yuehui Ma
摘要： After the morphological classification of the 18,190 $^{12}$CO molecular clouds, we further investigate the properties of their internal molecular gas structures traced by the $^{13}$CO($J=$ 1$-$0) line emissions. Using three different methods to extract the $^{13}$CO gas structures within each $^{12}$CO cloud, we find that $\sim$ 15$\%$ of $^{12}$CO clouds (2851) have $^{13}$CO gas structures and these $^{12}$CO clouds contribute about 93$\%$ of the total integrated flux of $^{12}$CO emission. In each of 2851 $^{12}$CO clouds with $^{13}$CO gas structures, the $^{13}$CO emission area generally does not exceed 70$\%$ of the $^{12}$CO emission area, and the $^{13}$CO integrated flux does not exceed 20$\%$ of the $^{12}$CO integrated flux. We reveal a strong correlation between the velocity-integrated intensities of $^{12}$CO lines and those of $^{13}$CO lines in both $^{12}$CO and $^{13}$CO emission regions. This indicates the H$_{2}$ column densities of molecular clouds are crucial for the $^{13}$CO lines emission. After linking the $^{13}$CO structure detection rates of the 18,190 $^{12}$CO molecular clouds to their morphologies, i.e. nonfilaments and filaments, we find that the $^{13}$CO gas structures are primarily detected in the $^{12}$CO clouds with filamentary morphologies. Moreover, these filaments tend to harbor more than one $^{13}$CO structure. That demonstrates filaments not only have larger spatial scales, but also have more molecular gas structures traced by $^{13}$CO lines, i.e. the local gas density enhancements. Our results favor the turbulent compression scenario for filament formation, in which dynamical compression of turbulent flows induces the local density enhancements. The nonfilaments tend to be in the low-pressure and quiescent turbulent environments of the diffuse interstellar medium.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
摘要： To study the chemical evolution during the formation of molecular clouds, we model three types of clouds with different density structures: collapsing spherical, collapsing ellipsoidal, and static spherical profiles. The collapsing models are better than the static models in matching the observational characteristics in typical molecular clouds. This is mainly because the gravity can speed up the formation of some important molecules (e.g., H$_2$, CO, OH) by increasing the number density during collapse. The different morphologies of prolate, oblate, and spherical clouds lead to differences in chemical evolution, which are mainly due to their different evolution of number density. We also study the effect of initial chemical compositions on chemical evolution, and find that H atoms can accelerate OH formation by two major reactions: O + H $\rightarrow$ OH in gas phase and on dust grain surfaces, leading to the models in which hydrogen is mainly atomic initially better match observations than the models in which hydrogen is mainly molecular initially. Namely, to match observations, initially hydrogen must be mostly atomic. The CO molecules are able to form even without the pre-existence of H$_2$. We also study the influence of gas temperature, dust temperature, intensity of interstellar radiation field and cosmic-ray ionization rate on chemical evolution in static clouds. The static CO clouds with high dust temperature, strong radiation field, and intensive cosmic rays are transient due to rapid CO destruction.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
Lixia Yuan
Ji Yang
Fujun Du
Xunchuan Liu
Yang Su
Qing-Zeng Yan
Xuepeng Chen
Yan Sun
Shaobo Zhang
Xin Zhou
Yuehui Ma
摘要： We look into the 2851 $^{12}$CO molecular clouds harboring $^{13}$CO structures to reveal the distribution of the projected angular separations and radial velocity separations between their internal $^{13}$CO structures. The projected angular separations are determined using the minimal spanning tree algorithm. We find that $\sim$ 50$\%$ of the angular separations fall in a narrow range of $\sim$ 3 - 7 arcmin with a median of $\sim$ 5 arcmin, and the corresponding radial velocity separations mainly range from $\sim$ 0.3 km s$^{-1}$ to 2.5 km s$^{-1}$. The mean and standard deviation of the angular separations of the internal $^{13}$CO structures within $^{12}$CO clouds appear to be universal, independent of the $^{12}$CO cloud angular areas and the counts of their internal $^{13}$CO structures. We also reveal a scaling relation between the $^{12}$CO cloud angular area and its harbored $^{13}$CO structure count. These results suggest there is a preferred angular separation between $^{13}$CO structures in these $^{12}$CO clouds, considering the distance effects. According to that, we propose an alternative picture for the assembly and destruction of molecular clouds: there is a fundamental separation for the internal structures of molecular clouds, the build-up and destruction of molecular clouds proceeds under this fundamental unit.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
摘要： Molecules reside broadly in the interstellar space and can be detected via spectroscopic observations. To date, more than 271 molecular species have been identified in interstellar medium or circumstellar envelopes. Molecular spectroscopic parameters measured in laboratory make the identification of new species and derivation of physical parameters possible. These spectroscopic parameters are systematically collected into databases, two of the most commonly used being the CDMS and JPL databases. While new spectroscopic parameters are continuously measured/calculated and added to those databases, at any point in time it is the existing spectroscopic data that ultimately limits what molecules can possibly be identified in astronomical data. In this work, we conduct a meta-analysis of the CDMS and JPL databases. We show the statistics of transition frequencies and their uncertainties in these two databases, and discuss the line confusion problem under certain physical environments. We then assess the prospects of detecting molecules in common ISM environments using a few facilities that are expected to be conducting spectroscopic observations in the future. Results show that CSST/HSTDM and SKA1-mid have the potential to detect some complex organic molecules, or even amino acids, with reasonable assumptions about ISM environments.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
摘要： The chemical differentiation of seven COMs in the extended region around Sgr B2 has been observed: CH$_2$OHCHO, CH$_3$OCHO, t-HCOOH, C$_2$H$_5$OH, and CH$_3$NH$_2$ were detected both in the extended region and near the hot cores Sgr B2(N) and Sgr B2(M), while CH$_3$OCH$_3$ and C$_2$H$_5$CN were only detected near the hot cores. The density and temperature in the extended region are relatively low. Different desorption mechanisms have been proposed to explain the observed COMs in cold regions but fail to explain the deficiency of CH$_3$OCH$_3$ and C$_2$H$_5$CN. We explored under what physical conditions the chemical simulations can fit the observations and explain the different spatial distribution of these species. We used the Monte Carlo method to perform a detailed parameter space study. We investigated how different mechanisms affect the results. All gas-grain chemical models based on static physics cannot fit the observations. The results based on evolving physical conditions can fit six COMs when $T\sim30-60$ K, but the best-fit temperature is still higher than the observed dust temperature of 20 K. The best agreement at $T\sim27$ K is achieved by considering a short-duration $\sim 10^2$ yr X-ray burst with $\zeta_{\mathrm{CR}}=1.3\times10^{-13}$ s$^{-1}$ when the temperature is 20 K. The reactive desorption is the key mechanism for producing these COMs and inducing the low abundances of CH$_3$OCH$_3$ and C$_2$H$_5$CN. The evolution of the extended region around Sgr~B2 may have begun with a cold, $T\le10$ K phase followed by a warm-up phase. When its temperature reached $T\sim20$ K, an X-ray flare from Sgr A* with a short duration of no more than 100 years was acquired, affecting strongly the Sgr B2 chemistry. The observed COMs retain their observed abundances only several hundred years after such a flare, which could imply that such short-term X-ray flares occur relatively often.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
摘要： Molecules reside broadly in the interstellar space and can be detected via spectroscopic observations. To date, more than 271 molecular species have been identified in interstellar medium or circumstellar envelopes. Molecular spectroscopic parameters measured in laboratory make the identification of new species and derivation of physical parameters possible. These spectroscopic parameters are systematically collected into databases, two of the most commonly used being the CDMS and JPL databases. While new spectroscopic parameters are continuously measured/calculated and added to those databases, at any point in time it is the existing spectroscopic data that ultimately limits what molecules can possibly be identified in astronomical data. In this work, we conduct a meta-analysis of the CDMS and JPL databases. We show the statistics of transition frequencies and their uncertainties in these two databases, and discuss the line confusion problem under certain physical environments. We then assess the prospects of detecting molecules in common ISM environments using a few facilities that are expected to be conducting spectroscopic observations in the future. Results show that CSST/HSTDM and SKA1-mid have the potential to detect some complex organic molecules, or even amino acids, with reasonable assumptions about ISM environments.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
Lixia Yuan
Ji Yang
Fujun Du
Xunchuan Liu
Shaobo Zhang
Zehao Lin
Jingfei Sun
Qing-Zeng Yan
Yuehui Ma
Yang Su
Yan Sun
Xin Zhou
摘要： We attempt to visually classify the morphologies of 18190 molecular clouds, which are identified in the $^{12}$CO(1-0) spectral line data over $\sim$ 450 deg$^{2}$ of the second Galactic quadrant from the Milky Way Imaging Scroll Painting project (MWISP). Using the velocity-integrated intensity maps of the $^{12}$CO(1-0) emission, molecular clouds are first divided into unresolved and resolved ones. The resolved clouds are further classified as non-filaments or filaments. Among the 18190 molecular clouds, $\sim$ 25 $\%$ are unresolved, $\sim$ 64$\%$ are non-filaments, and $\sim$ 11$\%$ are filaments. In the terms of the integrated flux of $^{12}$CO(1-0) spectra of the whole 18190 molecular clouds, $\sim$ 90$\%$ are from filaments, $\sim$ 9$\%$ are from non-filaments, and the rest $\sim$ 1$\%$ are from unresolved sources. Although non-filaments are dominant in the number of the discrete molecular clouds, filaments are the main contributor of $^{12}$CO emission flux. We also present the number distributions of physical parameters of the molecular clouds in our catalog, including their angular sizes, velocity spans, peak intensities of $^{12}$CO(1-0) emission, and $^{12}$CO(1-0) total fluxes. We find that there is a systematic difference between the angular sizes of the non-filaments and filaments, with the filaments tending to have larger angular scales. The H$_{2}$ column densities of them are not significantly different. We also discuss the observational effects, such as those induced by the finite spatial resolution, beam dilution and line-of-sight projection, on the morphological classification of molecular clouds in our sample.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
摘要： Water is crucial for the emergence and evolution of life on Earth. Recent studies of the water content in early forming planetary systems similar to our own show that water is an abundant and ubiquitous molecule, initially synthesized on the surfaces of tiny interstellar dust grains by the hydrogenation of frozen oxygen. Water then enters a cycle of sublimation/freezing throughout the successive phases of planetary system formation, namely, hot corinos and protoplanetary disks, eventually to be incorporated into planets, asteroids, and comets. The amount of heavy water measured on Earth and in early forming planetary systems suggests that a substantial fraction of terrestrial water was inherited from the very first phases of the Solar System formation and is 4.5 billion years old.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
Juan Li
Junzhi Wang
Xing Lu
Vadim Ilyushin
Roman A. Motiyenko
Qian Gou
Eugene A. Alekseev
Donghui Quan
Laurent Margules
Feng Gao
Frank J. Lovas
Yajun Wu
Edwin Bergin
Shanghuo Li
Zhiqiang Shen
Fujun Du
Meng Li
Siqi Zheng
Xingwu Zheng
摘要： Peptide bonds, as the molecular bridges that connect amino acids, are crucial to the formation of proteins. Searches and studies of molecules with embedded peptide-like bonds are thus important for the understanding of protein formation in space. Here we report the first tentative detection of propionamide (C2H5CONH2), the largest peptide-like molecule detected in space toward Sagittarius B2(N1) at a position called N1E that is slightly offset from the continuum peak. A new laboratory measurements of the propionamide spectrum were carried out in the 9-461 GHz, which provide good opportunity to check directly for the transition frequencies of detected interstellar lines of propionamide. Our observing result indicates that propionamide emission comes from the warm, compact cores in Sagittarius B2, in which massive protostellars are forming. The column density of propionamide toward Sgr B2(N1E) was derived to be 1.5\times 10^{16} cm^-2, which is three fifths of that of acetamide, and one nineteenth of that of formamide. This detection suggests that large peptide-like molecules can form and survive during star-forming process and may form more complex molecules in the interstellar medium. The detection of propionamide bodes well for the presence of polypeptides, as well as other complex prebiotic molecules in the interstellar medium.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
Lixia Yuan
Ji Yang
Fujun Du
Xunchuan Liu
Yang Su
Qing-Zeng Yan
Xuepeng Chen
Yan Sun
Shaobo Zhang
Xin Zhou
Yuehui Ma
摘要： We look into the 2851 $^{12}$CO molecular clouds harboring $^{13}$CO structures to reveal the distribution of the projected angular separations and radial velocity separations between their internal $^{13}$CO structures. The projected angular separations are determined using the minimal spanning tree algorithm. We find that $\sim$ 50$\%$ of the angular separations fall in a narrow range of $\sim$ 3 - 7 arcmin with a median of $\sim$ 5 arcmin, and the corresponding radial velocity separations mainly range from $\sim$ 0.3 km s$^{-1}$ to 2.5 km s$^{-1}$. The mean and standard deviation of the angular separations of the internal $^{13}$CO structures within $^{12}$CO clouds appear to be universal, independent of the $^{12}$CO cloud angular areas and the counts of their internal $^{13}$CO structures. We also reveal a scaling relation between the $^{12}$CO cloud angular area and its harbored $^{13}$CO structure count. These results suggest there is a preferred angular separation between $^{13}$CO structures in these $^{12}$CO clouds, considering the distance effects. According to that, we propose an alternative picture for the assembly and destruction of molecular clouds: there is a fundamental separation for the internal structures of molecular clouds, the build-up and destruction of molecular clouds proceeds under this fundamental unit.
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