分类： 天文学 >> 天文学 提交时间： 2023-02-19
摘要： HOCN and HNCO abundance ratio in molecular gas can tell us the information of their formation mechanism. We performed high-sensitivity mapping observations of HOCN, HNCO, and HNC$^{18}$O lines around Sagittarius B2 (Sgr B2) with IRAM 30m telescope at 3-mm wavelength. HNCO 4$_{04}$-3$_{03}$ and HOCN 4$_{04}$-3$_{03}$ are used to obtain the abundance ratio of HNCO to HOCN. The ratio of HNCO 4$_{04}$-3$_{03}$ to HNC$^{18}$O 4$_{04}$-3$_{03}$ is used to calculate the optical depth of HNCO 4$_{04}$-3$_{03}$. The abundance ratio of HOCN and HNCO is observed to range from 0.4% to 0.7% toward most positions, which agrees well with the gas-grain model. However, the relative abundance of HOCN is observed to be enhanced toward the direction of Sgr B2 (S), with HOCN to HNCO abundance ratio of $\sim$ 0.9%. The reason for that still needs further investigation.Based on the intensity ratio of HNCO and HNC$^{18}$O lines, we updated the isotopic ratio of $^{16}$O/$^{18}$O to be 296 $\pm$ 54 in Sgr B2.
分类： 天文学 >> 天文学 提交时间： 2023-02-19
Juan Li
Junzhi Wang
Xing Lu
Vadim Ilyushin
Roman A. Motiyenko
Qian Gou
Eugene A. Alekseev
Donghui Quan
Laurent Margules
Feng Gao
Frank J. Lovas
Yajun Wu
Edwin Bergin
Shanghuo Li
Zhiqiang Shen
Fujun Du
Meng Li
Siqi Zheng
Xingwu Zheng
摘要： Peptide bonds, as the molecular bridges that connect amino acids, are crucial to the formation of proteins. Searches and studies of molecules with embedded peptide-like bonds are thus important for the understanding of protein formation in space. Here we report the first tentative detection of propionamide (C2H5CONH2), the largest peptide-like molecule detected in space toward Sagittarius B2(N1) at a position called N1E that is slightly offset from the continuum peak. A new laboratory measurements of the propionamide spectrum were carried out in the 9-461 GHz, which provide good opportunity to check directly for the transition frequencies of detected interstellar lines of propionamide. Our observing result indicates that propionamide emission comes from the warm, compact cores in Sagittarius B2, in which massive protostellars are forming. The column density of propionamide toward Sgr B2(N1E) was derived to be 1.5\times 10^{16} cm^-2, which is three fifths of that of acetamide, and one nineteenth of that of formamide. This detection suggests that large peptide-like molecules can form and survive during star-forming process and may form more complex molecules in the interstellar medium. The detection of propionamide bodes well for the presence of polypeptides, as well as other complex prebiotic molecules in the interstellar medium.
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