Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Xunchuan Liu
Tie Liu
Zhiqiang Shen
Sheng-Li Qin
Qiuyi Luo
Yu Cheng
Qilao Gu
Tianwei Zhang
Fengyao Zhu
Sheng-Yuan Liu
Xing Lu
Rongbing Zhao
Weiye Zhong
Yajun Wu
Juan Li
Zhang Zhao
Jinqing Wang
Qinghui Liu
Bo Xia
Bin Li
Abstract： We have conducted a line survey towards Orion KL using the Q-band receiver of Tianma 65 m radio telescope (TMRT), covering 34.8--50 GHz with a velocity resolution between 0.79 km s$^{-1}$ and 0.55 km s$^{-1}$ respectively. The observations reach a sensitivity on the level of 1-8 mK, proving that the TMRT is sensitive for conducting deep line surveys. In total, 597 Gaussian features are extracted. Among them, 177 radio recombination lines (RRLs) are identified, including 126, 40 and 11 RRLs of hydrogen, helium and carbon, with a maximum $\Delta n$ of 16, 7, and 3, respectively. The carbon RRLs are confirmed to originate from photodissociation regions with a $V_{\rm LSR}\sim$9 km s$^{-1}$. In addition, 371 molecular transitions of 53 molecular species are identified. Twenty-one molecular species of this survey were not firmly detected in the Q band by Rizzo et al. (2017), including species such as H$_2$CS, HCOOH, C$_2$H$_5$OH, H$_2^{13}$CO, H$_2$CCO, CH$_3$CHO, CH$_2$OCH$_2$, HCN $v_2=1$, and CH$_3$OCHO $v_t=1$. In particular, the vibrationally excited states of ethyl cyanide (C$_2$H$_5$CN $v$13/$v$21) are for the first time firmly detected in the Q band. NH$_3$ (15,15) and (16,16) are identified, and they are so far the highest transitions of the NH$_3$ inversion lines detected towards Orion KL. All the identified lines can be reproduced by a radiative transfer model.
Peer Review Status:
Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Xunchuan Liu
Tie Liu
Zhiqiang Shen
Paul F. Goldsmith
Neal J. Evans
Sheng-Li Qin
Qiuyi Luo
Yu Cheng
Sheng-Yuan Liu
Fengyao Zhu
Ken'ichi Tatematsu
Meizhu Liu
Dongting Yang
Chuanshou Li
Li Cen
Juan Li
Xing Lu
Qilao Gu
Rongbing Zhao
Bing Li
Abstract： We report the first detection of radio recombination lines (RRLs) of ions heavier than helium. In a highly sensitive multi-band (12--50 GHz) line survey toward Orion KL with the TianMa 65-m Radio Telescope (TMRT), we successfully detected more than fifteen unblended $\alpha$ lines of RRLs of singly ionized species (XII) recombined from XIII. The Ka-band (35--50 GHz) spectrum also shows tentative signals of $\beta$ lines of ions. The detected lines can be successfully crossmatched with the the rest frequencies of RRLs of CII and/or OII. This finding greatly expands the connotation of ion RRLs, since before this work only two blended lines (105$\alpha$ and 121$\alpha$) of HeII had been reported. Our detected lines can be fitted simultaneously under assumption of local thermodynamic equilibrium (LTE). An abundance of CIII and OIII of 8.8$\times$10$^{-4}$ is obtained, avoiding the complexities of optical/infrared observations and the blending of RRLs of atoms. It is consistent with but approaches the upper bound of the value (10$^{-4}$--$10^{-3}$) estimated from optical/infrared observations. The effects of dielectronic recombination may contribute to enhancing the level populations even at large $n$. We expect future observations using radio interferometers could break the degeneracy between C and O, and help to reveal the ionization structure and dynamical evolution of various ionized regions.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Abstract： HOCN and HNCO abundance ratio in molecular gas can tell us the information of their formation mechanism. We performed high-sensitivity mapping observations of HOCN, HNCO, and HNC$^{18}$O lines around Sagittarius B2 (Sgr B2) with IRAM 30m telescope at 3-mm wavelength. HNCO 4$_{04}$-3$_{03}$ and HOCN 4$_{04}$-3$_{03}$ are used to obtain the abundance ratio of HNCO to HOCN. The ratio of HNCO 4$_{04}$-3$_{03}$ to HNC$^{18}$O 4$_{04}$-3$_{03}$ is used to calculate the optical depth of HNCO 4$_{04}$-3$_{03}$. The abundance ratio of HOCN and HNCO is observed to range from 0.4% to 0.7% toward most positions, which agrees well with the gas-grain model. However, the relative abundance of HOCN is observed to be enhanced toward the direction of Sgr B2 (S), with HOCN to HNCO abundance ratio of $\sim$ 0.9%. The reason for that still needs further investigation.Based on the intensity ratio of HNCO and HNC$^{18}$O lines, we updated the isotopic ratio of $^{16}$O/$^{18}$O to be 296 $\pm$ 54 in Sgr B2.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Xunchuan Liu
Tie Liu
Zhiqiang Shen
Paul F. Goldsmith
Neal J. Evans
Sheng-Li Qin
Qiuyi Luo
Yu Cheng
Sheng-Yuan Liu
Fengyao Zhu
Ken'ichi Tatematsu
Meizhu Liu
Dongting Yang
Chuanshou Li
Li Cen
Juan Li
Xing Lu
Qilao Gu
Rongbing Zhao
Bing Li
Abstract： We report the first detection of radio recombination lines (RRLs) of ions heavier than helium. In a highly sensitive multi-band (12--50 GHz) line survey toward Orion KL with the TianMa 65-m Radio Telescope (TMRT), we successfully detected more than fifteen unblended $\alpha$ lines of RRLs of singly ionized species (XII) recombined from XIII. The Ka-band (35--50 GHz) spectrum also shows tentative signals of $\beta$ lines of ions. The detected lines can be successfully crossmatched with the the rest frequencies of RRLs of CII and/or OII. This finding greatly expands the connotation of ion RRLs, since before this work only two blended lines (105$\alpha$ and 121$\alpha$) of HeII had been reported. Our detected lines can be fitted simultaneously under assumption of local thermodynamic equilibrium (LTE). An abundance of CIII and OIII of 8.8$\times$10$^{-4}$ is obtained, avoiding the complexities of optical/infrared observations and the blending of RRLs of atoms. It is consistent with but approaches the upper bound of the value (10$^{-4}$--$10^{-3}$) estimated from optical/infrared observations. The effects of dielectronic recombination may contribute to enhancing the level populations even at large $n$. We expect future observations using radio interferometers could break the degeneracy between C and O, and help to reveal the ionization structure and dynamical evolution of various ionized regions.
Peer Review Status:Awaiting Review
Subjects: Astronomy >> Astrophysical processes submitted time 2023-02-19
Juan Li
Junzhi Wang
Xing Lu
Vadim Ilyushin
Roman A. Motiyenko
Qian Gou
Eugene A. Alekseev
Donghui Quan
Laurent Margules
Feng Gao
Frank J. Lovas
Yajun Wu
Edwin Bergin
Shanghuo Li
Zhiqiang Shen
Fujun Du
Meng Li
Siqi Zheng
Xingwu Zheng
Abstract： Peptide bonds, as the molecular bridges that connect amino acids, are crucial to the formation of proteins. Searches and studies of molecules with embedded peptide-like bonds are thus important for the understanding of protein formation in space. Here we report the first tentative detection of propionamide (C2H5CONH2), the largest peptide-like molecule detected in space toward Sagittarius B2(N1) at a position called N1E that is slightly offset from the continuum peak. A new laboratory measurements of the propionamide spectrum were carried out in the 9-461 GHz, which provide good opportunity to check directly for the transition frequencies of detected interstellar lines of propionamide. Our observing result indicates that propionamide emission comes from the warm, compact cores in Sagittarius B2, in which massive protostellars are forming. The column density of propionamide toward Sgr B2(N1E) was derived to be 1.5\times 10^{16} cm^-2, which is three fifths of that of acetamide, and one nineteenth of that of formamide. This detection suggests that large peptide-like molecules can form and survive during star-forming process and may form more complex molecules in the interstellar medium. The detection of propionamide bodes well for the presence of polypeptides, as well as other complex prebiotic molecules in the interstellar medium.
Peer Review Status:Awaiting Review
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