分类: 核科学技术 >> 核材料与工艺技术 提交时间: 2023-08-14
摘要: Alloys of uranium and molybdenum are considered as the future of nuclear fuel and defense materials. However, surface corrosion is a fundamental problem in practical applications and storage. In this study, the static and dynamic evolution of carbon monoxide (CO) adsorption and dissociation on -U (1 0 0) surface with different Mo doping levels was investigated based on density functional theory and ab initio molecular dynamics. During the static calculation phase, parameters, such as adsorption energy, configuration, and Bader charge, were evaluated at all adsorption sites. Furthermore, the time-dependent behavior of CO molecule adsorption were investigated at the most favorable sites. The minimum energy paths for CO molecular dissociation and atom migration were investigated using the transition state search method. The results demonstrated that the CO on the uranium surface mainly manifests as chemical adsorption before dissociation of the CO molecule. The CO molecule exhibited a tendency to rotate and tilt upright adsorption. However, it is difficult for CO adsorption on the surface in one of the configurations with CO molecule in vertical direction but oxygen (O) is closer to the surface. Bader charge illustrates that the charge transfers from slab atoms to the 2* antibonding orbital of CO molecule and particularly occurs in carbon (C) atoms. The time is less than 100 fs for the adsorptions that forms embryos with tilt upright in dynamics evolution. The density of states elucidates that the overlapping hybridization of C and O 2p orbitals is mainly formed via the d orbitals of uranium and molybdenum (Mo) atoms in the dissociation and re-adsorption of CO molecule. In conclusion, Mo-doping of the surface can decelerate the adsorption and dissociation of CO molecules. A Mo-doped surface, created through ion injection, enhanced the resistance to uranium-induced surface corrosion.
分类: 光学 >> 量子光学 提交时间: 2023-02-19
摘要: We propose an effective approach for creating robust nonreciprocity of high-order sidebands, including the first-, second- and third-order sidebands, at microwave frequencies. This approach relies on magnon Kerr nonlinearity in a cavity magnonics system composed of two microwave cavities and one yttrium iron garnet (YIG) sphere. By manipulating the driving power applied on YIG and the frequency detuning between the magnon mode in YIG and the driving field, the effective Kerr nonlinearity can be strengthened, thereby inducing strong transmission non-reciprocity. More interestingly, we find the higher the sideband order, the stronger the transmission nonreciprocity marked by the higher isolation ratio in the optimal detuning regime. Such a series of equally-spaced high-order sidebands have potential applications in frequency comb-like precision measurement, besides structuring high-performance on-chip nonreciprocal devices.
分类: 光学 >> 量子光学 提交时间: 2023-02-19
摘要: Inspired by the capability of structured illumination microscopy in subwavelength imaging, many researchers devoted themselves to investigating this methodology. However, due to the free propagating feature of the traditional structured illumination fields, the resolution can be only improved up to double times compared with the diffractied limited microscopy. Besides, most of the previous studies, relying on incoherent illumination sources, are restricted to fluorescent samples. In this work, a subwavelength nonfluorescent imaging method is proposed based on the terahertz traveling wave and plasmonics illumination. Excited along with a metal grating, the spoof surface plasmons are employed as the plasmonics illumination. When the scattering waves with the SSPs illumination are captured, the high order spatial frequency components of the sample are already encoded into the obtainable low order ones. Then, an algorithm is summarized to shift the modulated SF components to their actual positions in the Fourier domain. In this manner, high order SF components carrying the fine information are introduced to reconstruct the desired imaging, leading to an improvement of the resolution up to 0.12 lambda. Encouragingly, the resolution can be further enhanced by tuning the working frequency of the SSPs. This method holds promise for some important applications in terahertz nonfluorescent microscopy and sample detection with weak scattering.
分类: 核科学技术 >> 粒子加速器 提交时间: 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
摘要: The 500 MHz 5-cell superconducting RF (SRF) cavity was designed aiming to be a candidate cavity for high current accelerators. A copper prototype cavity and a niobium cavity were fabricated at SINAP in 2012. In order to ensure these cavities get the desired frequency and a good field flatness higher than 98%, frequency control was implemented in the manufacturing process and pre-tuning has been done using a simple pre-tuning frame based on the bead-pull pre-tuning method. Then, TM010- mode frequency within 5 kHz from the target frequency was achieved and the field flatness reached 98.9% on the copper prototype cavity. Finally, the same procedure was applied to the niobium cavity to obtain a field flatness better than 98% which benefited the cavity performance in the vertical testing.
分类: 核科学技术 >> 粒子加速器 提交时间: 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
摘要: The low level radio frequency (LLRF) system for booster accelerator at Shanghai Synchrotron Radiation Facility (SSRF) was upgraded by a digital controller based on field programmable gate array (FPGA) technology. Parameters of voltage, frequency and field flatness in the two 5-cell cavities are controlled to meet the requirements of booster. In this article, the ramping curve of cavity voltage, amplitude and phase control loop with vector sum of the two 5-cell cavities, tuning loop and field flatness loop are analyzed and discussed in detail. A different method in tuning loop is adopted due to the limitations of ADC channels. The function realizes energy ramping of electron beam from 150 MeV to 3.5 GeV with a repetition rate of 2 Hz. With the new LLRF controller, the phase stability at ramping mode in 10 hours long operation is improved from � 1.5� (RMS) with open loop to � 0.15� (RMS) with close loop, while the detuning phase and field flatness are maintained to within � 2癮nd � 1%, respectively.
分类: 核科学技术 >> 粒子加速器 提交时间: 2023-06-18 合作期刊: 《Nuclear Science and Techniques》
摘要: Surface preparation is an important processing in production procedures of superconducting niobium cavities, deciding whether the performance of the niobium cavities can meet the specifications. A series of surface preparation methods and relevant apparatuses have been constructed at Shanghai Institute of Applied Physics (SINAP) and the standard procedures of cavity processing were established and successfully applied to different types of cavities. With standard surface preparation procedures on the 500 MHz 5-cell niobium cavity, the cavity accelerating voltage at T=4.2 K reached 7.5 MV while its quality factor was still higher than 1�109. The accelerating gradient of the IMP-HWR010 cavity reached 4.9 MV/m with the quality factor of better than 3�108 at 4.2 K.