提交时间: 2017-05-02
摘要: Development of novel biocompatible nanomaterials has provided insights into their potential biomedical applications. Bulk fabrication of the nanomaterials in the form of coatings remains challenging. Here, we report hydroxyapatite [HA]/graphene-nanosheet
分类: 天文学 >> 天文学 提交时间: 2023-02-19
摘要: The burst mode of accretion in massive star formation is a scenario linking the initial gravitational collapse of parent pre-stellar cores to the properties of their gravitationally unstable discs and of their accretion-driven bursts. In this study, we present a series of high-resolution 3D radiation-hydrodynamics numerical simulations for young massive stars formed out of collapsing 100 Mo molecular cores spinning with several values of the ratio of rotational-to-gravitational energies beta=5%-9%. The models include the indirect gravitational potential caused by disc asymmetries. We find that this modifies the barycenter of the disc, causing significant excursions of the central star position, which we term stellar wobbling. The stellar wobbling slows down and protracts the development of gravitational instability in the disc, reducing the number and magnitude of the accretion-driven bursts undergone by the young massive stars, whose properties are in good agreement with that of the burst monitored from the massive protostar M17 MIR. Including stellar wobbling is therefore important for accurate modeling disc structures. Synthetic ALMA interferometric images in the millimeter waveband show that the outcomes of efficient gravitational instability such as spiral arms and gaseous clumps can be detected for as long as the disc is old enough and has already entered the burst mode of accretion.
提交时间: 2017-05-02
摘要: Here we report aluminum-alumina composite coatings fabricated by flame spraying for potential marine applications against both corrosion and wear. Microstructure examination suggested dense coating structures and the evenly distributed alumina splats form
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: Titania-hydroxyapatite (HA) nanocomposites were fabricated by wet chemical synthesis approach. HA exhibited crystallographic orientation of nucleation on nano titania particle, forming the composite particles with titania being partially enwrapped with HA. Microstructural characterization by high res- olution transmission electron microscopy revealed coherent interfacial bond of (110) and (222) planes of HA crystal with (101) plane of anatase. The HA layer promoted significantly recruitment of Escherichia coli bacteria onto the titania-based particles for subsequent photocatalytic killing. Less extent of enwrapping of HA on titania particle, as accomplished by increasing the aging time of HA suspension, gave rise to better capability of photocatalytic degradation of methylene blue and sterilization of the bacteria. The novel HA-enwrapped titania powder shows great potential for environmental applications.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: Hexamethylene diisocyanate can chemically react with the onium ion produced by the oxidation of propylene carbonate and in situ generate a novel interfacial layer that is stable at high potential. With an appropriate thickness of this film, LiNi1/3Co1/3Mn1/3O2 presents significantly improved rate and cycle performances when tested between 2.5 and 4.6 V (vs. Li/Li+).
分类: 光学 >> 量子光学 提交时间: 2023-02-19
摘要: Surface plasmons in graphene provide a compelling strategy for advanced photonic technologies thanks to their tight confinement, fast response and tunability. Recent advances in the field of all optical generation of graphene plasmons in planar waveguides offer a promising method for high speed signal processing in nanoscale integrated optoelectronic devices. Here, we use two counter propagating frequency combs with temporally synchronized pulses to demonstrate deterministic all optical generation and electrical control of multiple plasmon polaritons, excited via difference frequency generation (DFG). Electrical tuning of a hybrid graphene fibre device offers a precise control over the DFG phase matching, leading to tunable responses of the graphene plasmons at different frequencies across a broadband (0 - 50 THz) and provides a powerful tool for high speed logic operations. Our results offer insights for plasmonics on hybrid photonic devices based on layered materials and pave the way to high speed integrated optoelectronic computing circuits.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: In this work, we investigate the influence of oxygen non-stoichiometry on the characteristics of LiNi0.8Co0.1Mn0.1O2 cathode material. Among the investigated samples, the level of Ni/Li disorder in the bulk and the thickness of auto-generated layer on the surface share the same trend as the amount of oxygen loss in LiNi0.8Co0.1Mn0.1O2 materials. It indicates that the aforementioned key structural in- stabilities should be tightly related to the oxygen defects and the induced structural relaxation. As a consequence of structural entirety, the sample with the least defects presents the highest discharge capacity (192.9 mAhg 1 at 0.1C), the best rate capability (160.1 mAhg 1 at 5C), and the most stable cyclibility (89.9% at 200th). Our results demonstrate that oxygen deficiency plays a key role to determine the electrochemical performance of high-nickel cathode materials.
分类: 天文学 >> 天体物理学 提交时间: 2024-05-20
摘要: Context : Understanding the mechanisms that launch and shape powerful relativistic jets from supermassive black holes (SMBHs) in high-redshift active galactic nuclei (AGN) is crucial for probing the co-evolution of SMBHs and galaxies over cosmic time. Aims :We study the high-redshift ($z=3.396$) blazar OH~471 to explore the jet launching mechanism in the early Universe. Methods : Using multi-frequency radio monitoring observations and high-resolution Very Long Baseline Interferometry imaging over three decades, we study the milliarcsecond structure and long-term variability of OH~471. Results : Spectral modelling of the radio flux densities reveals a synchrotron self-absorbed spectrum indicating strong magnetic fields within the compact core. By applying the flux freezing approximation, we estimate the magnetic flux carried by the jet and find that it reaches or exceeds theoretical predictions for jets powered by black hole spin energy via the Blandford-Znajek mechanism. This implies that OH~471 was in a magnetically arrested disk (MAD) state where the magnetic flux accumulated near the horizon regulates the accretion flow, allowing efficient extraction of black hole rotational energy. Conclusions : Our study demonstrates the dominance of MAD accretion in powering the prominent radio flares and relativistic jets observed in the radio-loud AGN OH~471 and statistical studies of large samples of high-redshift AGN will shed light on the role of MAD accretion in launching and accelerating the earliest relativistic jets.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: A surface protective structure to efficiently improve the cyclic stability and lifetime of the lithium metal electrode is investigated. By volu- metrically confining plated lithium metal in the inter-space of a ceramic porous layer and isolating the confined lithium via a rein- forced skin-layer from attack by electrolyte solvents, the coulombic efficiency of the protected lithium metal electrode reaches very high values of $97–99%.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: Detection of malignant cells from malignant effusion is crucial to establish or adjust therapies of patients with cancer. The conventional qualitative detection in malignant pleuroperitoneal effusion is cytological analysis, which is time-consuming and complicated. Therefore, a faster and more convenient detection strategy is urgently needed. In this study, we report a rapid method to detect malignant cells from malignant pleuroperitoneal effusion (hydrothorax and ascites) of patients using IR-808, a tumor-targeted near-infrared (NIR) fluorescent heptamethine dye (tNRI dye), which exhibited superior labeling efficacy without specific conjugation to biomarkers. The targeted imaging performance toward malignant cells using IR-808 was confirmed by comparing with normal cells, and the fluorescence stability assay of IR- 808 in malignant effusion was performed from 1 h to 48 h. In order to save time and dose, the incubation time and concentration were optimized to 10 min and 5 mM, which were used to detect malignant cells from 28 clinical samples of malignant pleuroperitoneal effusion. The results revealed that IR-808 could be internalized selectively by malignant cells of samples, and these malignant cells could be easily distinguished from normal cells under a fluorescence microscope. The positive rates between cytological analysis and the IR-808 staining method were 86% (24/28) and 79% (22/28), respectively. An excellent concordance level (Kappa 1⁄4 0.752, P < 0.001) was observed between the two methods. Our results indicated that IR-808, a new NIR fluorescent heptamethine dye with unique optical imaging and tumor targeting properties, could provide a fast and simple way to detect a broad spectrum of malignant cells from malignant pleuroperitoneal effusion in patients.
分类: 物理学 >> 普通物理:统计和量子力学,量子信息等 提交时间: 2017-05-02
摘要: A new facile scalable method has been developed to synthesize silicon oxycarbide (SiOC)/carbon nanohybrids using difunctional dental methacrylate monomers as solvent and carbon source and the silane coupling agent as the precursor for SiOC. The content (from 100% to 40% by mass) and structure (ratio of disor- dered carbon over ordered carbon) of the free carbon matrix have been systematically tuned by varying the mass ratio of methacryloxy- propyltrimethoxysilane (MPTMS) over the total mass of the resin monomers from 0.0 to 6.0. Compared to the bare carbon anode, the introduction of MPTMS significantly improves the electrochemical performance as a lithium-ion battery anode. The initial and cycled discharge/charge capacities of the SiOC/C nanohybrid anodes reach maximum with the MPTMS ratio of 0.50, which displays very good rate performance as well. Detailed structures and electrochemical performance as lithium-ion battery anodes have been systematically investigated. The structure−property correlation and corresponding mechanism have been discussed.